Organic carbon transport in the Columbia River     

Clifford N. Dahm  Stanley V. Gregory  P. Kilho Park 《Estuarine, Coastal and Shelf Science》1981,13(6):645-658

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Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?     

Sandro Fuzzi  Maria Cristina Facchini  Stefano Decesari  Emanuela Matta  Mihaiela Mircea 《Atmospheric Research》2002,64(1-4)

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.  相似文献   

Kinetics of Disproportionation of Inorganic Polysulfides in Undersaturated Aqueous Solutions at Environmentally Relevant Conditions     

A. Kamyshny  A. Goifman  D. Rizkov  O. Lev 《Aquatic Geochemistry》2003,9(4):291-304

The rate of the reversible homogeneous disproportionation of polysulfides was studied by following the optical absorbance of polysulfide solutions in a continuous plug flow reactor equipped with an on-line photometric detector. In order to avoid heterogeneous slow reactions involving sulfur colloids or precipitate, the reaction was initiated by an abrupt pH change from an undersaturated solution containing predominantly tetrasulfide species to a pH where pentasulfide is the dominant species. The disproportionation was found to follow first order reversible reaction dynamics. At environmentally relevant conditions the characteristic time of the disproportionation reaction is of the order of 10 s. This characteristic time implies that necessary conditions for speciation of the different polysulfide species by chromatography or another separation and subsequent quantification scheme should be of the order of 1 s.  相似文献   

微区分析在地质研究中的应用          下载免费PDF全文

杨明明 《岩石矿物学杂志》1997,16(4):374-379

微区分析是现代分析技术在地质研究应用中的一个重要领域。通过电子探针对矿物的微区分析，提供了矿床成因理论研究的新依据。本文以金银互化物的研究为例，讨论了在不同在因类型矿床中，金－银构成一个连续的类质同象系列，且变化是有规律可循，其微量元素的含量与该矿床成矿地质环境和相应的地球化学场有关，从而为找矿提供了新的地质信息，拓宽了寻找同类伴生元素矿床或发现新类型矿床的途径。  相似文献   

An invariance in the carbazoles of petroleum     

张春明赵红静  胡伯良 《中国地球化学学报》2005,24(3):253-256

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.  相似文献   

Interaction of glucose and cellulose with hydrogen sulphide and polysulphides     

M.E.C. Moers  J.W. de Leeuw  H.C. Cox  P.A. Schenck 《Organic Geochemistry》1988,13(4-6)

This paper describes simulation experiments in which glucose and cellulose were reacted with polysulphide and hydrogen sulphide at ambient temperatures in an aqueous environment. Organic sulphur containing compounds were formed that yield several thiophenes upon pyrolysis/evaporation. The experiments show that interaction of carbohydrates with hydrogen sulphide or polysulphides is a possible way for carbohydrates to react in very recent sediments. From the results of this study it can be concluded that carbohydrate carbon can be preserved in sediments in a form that is resistant to microbial attack and that will have a greater potential for survival during diagenesis than the carbohydrate precursor.  相似文献   

Identification and occurrence of novel C₃₆–C₅₄ 3,4-dialkylthiophenes with an unusual carbon skeleton in immature sediments     

M.E.L. Kohnen  T.M. Peakman  J.S.Sinninghe Damste  J.W. de Leeuw 《Organic Geochemistry》1990,16(4-6)

A series of novel long-chain 3,4-dialkylthiophenes (C₃₆–C₅₄) was identified in a number of sediments ranging from Pleistocene to Cretaceous. The identifications were based on mass spectral characterisation, desulphurisation and mass spectral data of synthesised model compounds. These organic sulphur compounds are probably formed by sulphur incorporation into mid-chain dimethylalkadienes with two methylenic double bonds. These putative precursor lipids are unprecedented and may be considered rather unusual. The distribution of 3,4-dialkylthiophenes in sediments varies considerably with the depositional palaeoenvironment, indicating that these compounds have a potential as molecular markers reflecting changes in palaeoenvironment.  相似文献   

Prediction of the abiotic degradability of organic compounds in the troposphere     

Hans Güsten  Leo Klasinc  Dubravko Marić 《Journal of Atmospheric Chemistry》1984,2(1):83-93

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.  相似文献   

Effect of system variables and particle size on physical characteristics of air sparging plumes     

Daniel M. Baker  Craig H. Benson 《Geotechnical and Geological Engineering》2007,25(5):543-558

Air was injected through a well in a thin transparent tank filled with saturated glass beads to study how the size and air saturation of air sparging plumes are affected by particle size and gradation; operational parameters such as injection pressure, well depth, injection pressure pulsing; and well outlet configuration. V-shaped air plumes with an apex between 40° and 60° were obtained for all tests. The air pressure required to initiate sparging agreed closely with the sum of the air entry pressure and the hydrostatic pressure, with higher initiation pressures required in the fine and well-graded beads. Higher air flow rates and air saturations were obtained in coarser beads at a given pressure, and the variation in flow rate was consistent with estimated air permeabilities. Peak average air saturations were 28–56% for the coarse-medium beads, 10% for the well-graded beads, and 8% for the fine beads. Air saturation and the radius of influence increased modestly (<40%) as the normalized injection pressure exceeded 0.1. Radius of influence increased by approximately a factor of two as the well depth increased, but leveled off once the ratio of radius of influence to well depth reached 0.60–1.05. Pulsing of injection pressure had no effect on the initiation pressure, air flow rate, or air saturation, but increased the size of the air plume and the radius of influence slightly (<15%). Well outlet configuration had only a slight affect the radius of influence (<10%), air saturation (<10%), or air flow rate (<12%). Dye testing showed that water surrounding the air plume circulated during continuous and pulsed sparging. However, pulsed sparging resulted in greater and more defined circulation of water within and adjacent to the air plume, which should reduce mass transfer limitations during sparging.  相似文献   

水资源中氯代烃污染物的去除方法   总被引：3，自引：0，他引：3  

李琳  刘菲 《黄金地质》2002,8(2):74-76

随着工业化的发展。氯代有机溶剂使用越来越广泛。并且难于去除。在20世纪90年代初期，人们就已认识到用Fe^0恢复污染的地下水的潜力。国外正在研究帮使用扔几种还原挥发性氯代烃的还原反应介质，尤其要提高的是双金属反应系统，反应速度快，而且脱Cl中国难解产物少，目前国也只停留在实验室研究阶段，个别做了地上反应器的验证实验，它的脱Cl机理、介质钝化和完全脱Cl问题还有待于进一步研究。  相似文献